PbGa2S4Dy3+

A prototype of a small–sized 4.38-5.5 micron laser emitter
Each type of visual aid has pros and cons that must be evaluated to ensure it will be beneficial to the overall presentation. Before incorporating visual aids into speeches, the speaker should understand that if used incorrectly, the visual will not be an aid, but a distraction.

Planning ahead is important when using visual aids. It is necessary to choose a visual aid that is appropriate for the material and audience. The purpose of the visual aid is to enhance the presentation. Each type of visual aid has pros and cons that must be evaluated to ensure it will be beneficial to the overall presentation. Before incorporating visual aids into speeches, the speaker should understand that if used incorrectly, the visual will not be an aid, but a distraction. Planning ahead is important when using visual aids. It is necessary to choose a visual aid that is appropriate for the material and audience. The purpose of the visual aid is to enhance the presentation.


Diagram of the energy levels of the Dy3+ ion

the luminescence (red) and generation (blue) spectra of the PbGa2S4:Dy3+ crystal

Generation was obtained at two transitions of the ion Dy3+ 6H11/2 — 6H13/2 и 6H9/2 — 6H11/2 according to a cascade scheme.
The pumping was carried out with an IAG-Nd3+ laser at a wavelength of 1.38 microns. Measurement of the lifetime of levels 6H9/2, 6H11/2 and 6H13/2 showed that it is equal to 160 microseconds, 2 ms and 5.6 ms. This means that the 6H11/2 — 6H13/2 and 6H9/2 — 6H11/2 laser junctions are self-limited. Generation develops first at the 6H11/2 — 6H13/2 transition, and then with increasing pumping energy at the 6H9/2 — 6H11/2 transition.
The figures showing the luminescence and generation spectra show that generation is achieved simultaneously on six lines.: three in the range of 4.38–4.7 microns and three in the range of 5.2–5.5 microns.
A pulsed and continuous generation mode is obtained. The pulse energy was 30 MJ with a differential efficiency of 8%. The duration of the generation pulses reached 1.5 ms. A prototype of a medium-IR laser with generation from 4.38–5.5 microns on a PbGa2S4 crystal activated by dysprosium ions.
The PbGa2S4:Dy3+ laser material was highly appreciated by the world scientific community, was noted in the article Fifty years of advances in solid-state laser materials, G. Boulon, Optical materials 34 (2012), 499-512, and was among the world's best achievements.

Picture 15 (a, b). Photographs of experimental soft tissue wounds in rats exposed to laser radiation in the wavelength range of 4.38–5.5 microns with a duration of 6 minutes

Picture 16 (c, d). Photographs of experimental soft tissue wounds in rats during the natural healing process on days 3 (c) and 17

Together with the staff of the Medical University, we investigated the dynamics of the microbicidal activity of neutrophil granulocytes in animals with soft tissue wounds using the created prototype of laser radiation.
All the animals were divided into three groups. The first group was a control group. In the second group of animals, the wound surface was irradiated with a laser for 4 minutes daily with an interval of 24 hours for 14 days (Picture 15 a. b). In the third group, under the same conditions, the duration of exposure was 6 minutes.
The material was collected before the start of the experiment, as well as on the 1st, 4th, 7th and 14th days. Blood smears and exudate prints were stained for Pigarevsky cationic protein, and myeloperoxidase activity was determined by Sat. It was found that during the natural course of the wound process, complete repair did not occur in the rats of the control group by the 17th day of the experiment, as evidenced by the presence of visually detectable skin defects (picture c, d). Irradiation of an experimental rat soft tissue wound for 4 or 6 minutes over 8 days has a pronounced activating effect on the oxygen-dependent and oxygen-independent microbicidal systems of neutrophil granulocytes (NG), which leads to a multiple acceleration of reparative processes in the wound (Picture 15 a, b). The area of the rat wound during the natural healing process decreased by 17 days 8.5%, and when irradiated with a laser for 8 days — by 76.5%. Given the time difference during these experiments, it can be argued that the healing rate when wounds are irradiated with a medium-IR laser is 20 times faster than the rate of the natural healing process.
PbGa2S4:Dy3+

It is of interest in the future to irradiate rat wounds not for 4 or 6 minutes per day, but for a longer time, up to a continuous radiation regime. Increasing the duration of exposure to wounds with medium infrared radiation may further accelerate their healing.
After additional research, this method can be used in various fields of medicine: disaster medicine, military medicine (in mobile or hospital settings), etc., when rapid and effective wound treatment is of paramount importance for preserving the patient's life and health.
In 2016, the laser on the PbGa2S4:Du3+ element was improved. Generation was obtained at three more wavelengths — 2.4, 4.3 and 5.4 microns. These results appeared in the study of other energy transitions in the laser-active PbGa2S4:Dy3+ material associated with the energy levels 6Н9/2 + 6F11/2 or 6Н11/2. A PbGa2S4:Dy3+-based laser was pumped by radiation from an unsynchronized Nd:YAG laser or by radiation from a laser diode corresponding to the absorption peak of PbGa2S4:Dy3+. The PbGa2S4:Dy3+ crystal was placed in a stable optical resonator with mirrors selected according to the required generation wavelength.

Наши публикации

1. Samvel Avanesov, Valeriy Badikov, Aleksey Tyazhev, Dmitrii Badikov, Vladimir Panyutin, Georgi Marchev, Galina Shevyrdyaeva, Konstantin Mitin, Frank Noack, Polina Vinogradova, Nadezhda Schebetova, Valentin Petrov, and Albert Kwasniewski, "PbIn6Te10: new nonlinear crystal for three-wave interactions with transmission extending from 1.7 to 25 µm," Opt. Mater. Express 1, 1286-1291 (2011).

https://doi.org/10.1364/OME.1.001286

2. Avanesov S.A., Badikov D.V., Badikov V.V., V.L. Panyutin V.L., Petrov V., Shevyrdyaeva G.S., Martynov A.A., Mitin K.V. Phase equilibrium studies in the PbTe–Ga2Te3 and PbTe–In2Te3 systems for growing new nonlinear optical crystals of PbGa6Te10 and PbIn6Te10 with transparency extending into the far-IR. Journal of Alloys and Compounds. 2014. No 612. P. 386–391. https://doi.org/10.1016/j.jallcom.2014.05.168

3. A. Ionin, I. O. Kinyaevskiy, Y. M. Klimachev, A. A. Kotkov, V. V. Badikov, and K. V. Mitin, "Frequency conversion of molecular gas lasers in PbIn6Te10 crystal within mid-IR range," Opt. Lett. 41, 2390-2393 (2016). doi: 10.1364/OL.41.002390

4. H. Jelinkova, M. E. Doroshenko, V. V. Osiko, M. Jelinek, J. Sulc, M. Nemec, D. Vyhlidal, V. V. Badikov, D. V. Badikov. Dysprosium thiogallate laser: source of mid-infrared radiation at 2.4, 4.3, and 5.4 µm. Applied Physics A 122(8), August 2016. DOI: 10.1007/s00339-016-0223-4

5. Yu M Andreev, V V Badikov, A A Ionin, I O Kinyaevskiy, Yu M Klimachev, A A Kotkov, G V Lanskii and V A Svetlichnyi. Optical properties of PbIn6Te10 in the long-wave IR. Laser Physics Letters, Volume 13, Number 12. http://dx.doi.org/10.1088/1612-2011/13/12/125405

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